Mixing/Combining color schemes

2021.09.16 12:43 Ioelet Mixing/Combining color schemes

I'm planning to start painting my W40K army at the moment and read some good articles about color theory. I understand concepts like analogous, complementary, triadic or split complement color schemes as well as saturation, black/white/grey and brown-ish tones. So, I have some ideas how to paint the models of my basic units.
Now to my question/problem. An Army consists of different models/units that have different narrative concepts. Unit 1 might be a rusty machine, Unit 2 a blood-soaked beast, Unit 3 a transparent gost-like creature.
Painting all of them in the same color scheme sounds like limiting the possibilies. If I choose a "blood" red color for one unit - does that mean redish rust is off the table on the other unit if I want to keep the colors in harmony?

Are there any rules of combining two or more color schemes that have some kind of scheme-level harmony like the color-level harmony of the colors?
One example: How could i include a beauty like this in a non-pastel blue and gold color scheme?
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